Added apps in Bootable PE do not run

I have made the bootable PE usb multiple times, each option, whether it is 32 BIT UEFI or 64, gives me the option of adding custom portable apps, or directories, so I pick some useful portable apps, missing from the AOEMEI list from here

Problem is, the directory is visible on the USB live desktop, but none of them run, double click them nothing happens.

What do I have to do to make them run?


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