Added apps in Bootable PE do not run

I have made the bootable PE usb multiple times, each option, whether it is 32 BIT UEFI or 64, gives me the option of adding custom portable apps, or directories, so I pick some useful portable apps, missing from the AOEMEI list from here https://portableapps.com

Problem is, the directory is visible on the USB live desktop, but none of them run, double click them nothing happens.

What do I have to do to make them run?

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